Synthesis and Characterization of Poly(o-toluidine) Doped with Camphor Sulphonic Acid

نویسندگان

  • S Dhanavel
  • E A K Nivethaa
  • D Sangamithirai
  • V Narayanan
چکیده

Among the conducting polymers, Polyaniline and its derivatives have been studied extensively in the last decade with improvements in processing having the key role in establishing the intrinsic electrical properties. In the present paper, the camphor sulphonic acid [CSA] doped Poly (o-toluidine) [POT] was prepared using chemical oxidative polymerization method. The prepared CSA doped POT was characterized using XRD, FTIR and UV-Vis analysis. The XRD pattern showed the amorphous nature of the Polymer. The FTIR pattern shows the various stretching and bending modes of POT. UV-Vis analysis exhibits emaraldine state of the polymeric system. Conductivity of the sample was studied by impedance spectroscopy. Keywordsconducting polymer; POT; CSA; XRD; FTIR; UV-Vis analysis

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Study on the Thermal Decomposition Kinetics and Calculation of Activation Energy of Degradation of Poly(o-toluidine) Using Thermogravimetric Analysis

Thermo Gravimetric Analysis (TGA) analysis was employed to investigate activation energy (Ea) for the process of degrading of poly(o-toluidine) (POT) applying Horwitz & Metzger, Coats & Redfern and Chan et al., methods. POT was synthesized by chemical oxidative polymerization method using Ammonium per Sulphate (APS) as an oxidant while Dodecylbenzene Sulphonic Acid (DBSA) and sul...

متن کامل

Electrosynthesis, Characterization and Corrosion Inhibition Study of DBSA-doped Polyaniline Coating on 310 Stainless Steel

The synthesis of polyaniline doped with dodecylbenzene sulphonic acid (Pani-DBSA) coatings on 310 stainless steel (310 SS) surfaces has been investigated by using the galvanostatic method. The synthesized coatings were characterized by Fourier Transform Infrared Spectroscopy (FT-IR), UV-Visible absorption spectrometry and Scanning Electron Microscopy (SEM...

متن کامل

Effect of solvent polarity on fluoroscence spectra of camphor Sulphonic acid doped Polyaniline

The Camphor sulphonic acid doped polyaniline (CSA-PANi)is synthesized by chemical polymerization method and then characterized by using UV-Visible and FTIR. The surface morphology is studied by SEM and AFM techniques. The degree of crystallinity of PANiis studied by XRD and redox behaviour by cyclic voltametry. Thermal stability of the doped polymer is investigated by TGA and DSC.The fluorescen...

متن کامل

Synthesis and characterization of poly (AAm-co-AAc)/NaA nanocomposite and removal of methylene blue with it

The nanocomposites of poly (Acryl amide-co-Acrylic acid) with different contents of NaAzeolite were prepared using ammonium persulfate as an initiator and N, N′-methylenebisacrylamide as the crosslinker. The morphology was characterized by SEM and the structure ofnanocomposite materials was studied with XRD and FT-IR that showed the interaction betweenporous materials and poly (AAm-co-Aac). The...

متن کامل

Synthesis and Fluorescence Spectroscopy of Sulphonic Acid-Doped Polyaniline When Exposed to Oxygen Gas

Three sulphonic acid-doped polyanilines were synthesized through chemical oxidation at low temperature (0-5 C) and potential of these polymers as sensing agent for O2 gas detection in terms of fluorescence quenching was studied. Sulphuric acid, dodecylbenzene sulphonic acid (DBSA) and camphor sulphonic acid (CSA) were used as doping agents. All polymers obtained were dark green powder. Polymers...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2014